Ferrous sulfate, also called iron sulfate, is a form of iron with several uses as a lawn treatment. In all cases, immediate medical attention should be obtained (fisher scientific, 2009). Iron sulphide is also used as a laboratory chemical for the preparation of hydrogen sulphide gas. (S.F.). Empty containers represent a risk of fire, the residue must be evaporated under an extractor hood. A Texas-based oil company operates a producing field in west Texas. With a history of iron sulfide related problems, one of their wells experienced excessive workover costs and downtime. If the plant is opened and the deposit of ferrous sulfide is exposed to air, its exothermic oxidation may raise temp of gases and vapors in the vicinity. Hemoglobin carries oxygen through your blood to tissues and organs. Biology and biogeochemistry. IDENTIFICATION. The iron in the steel reacts with hydrogen sulfide to create an iron crust scale on the metal surface. iron(II) sulphate) or ferrous sulfate is the chemical compound with the formula (FeSO4), known since ancient times as copperas. It is a microfertilizer containing ferrous iron-that is, iron in the most accessible form for plant cells. Iron sulphide has uses compatible with sulfates. Iron sulfide is mainly used in the manufacture of ceramics. Material Safety Data Sheet Iron (II) Sulfide. Iron Sulfide (FeS) & Iron Disulfide (FeS2) Iron Pyrite Physical Properties. Iron sulfide is the most prominent contaminant in natural-gas pipelines and compression equipment in pipeline, refinery, gathering, and storage applications. In the purification of crude phosphoric acid, iron sulphide is used as a reducing agent to remove heavy impurities form phosphoric acid. Iron sulfide is used in the alloy and stainless steel industries to control the embrittlement of hydrogen. 3. If you do not feel well, you should seek medical attention and show the product label as much as possible. The iron and steel industry uses iron sulfide as a resulfurization agent in the manufacture of carbon, alloy and stainless steel free cutting steels. If it does not breathe, artificial respiration should be given. Royal Society of Chemistry. Ferrous sulfide reacts in acid media to form ferrous oxide and hydrogen sulphide vapors that are extremely toxic. Iron sulphide, also known as ferrous sulphide, is a chemical compound used in alloy and stainless steel industries to control hydrogen embrittlement. When sedimentary deposits containing large quantities of sulfide minerals are exposed to air and water, they rapidly oxidize to produce iron and other metals, sulfate, and acid. If breathing is difficult, give oxygen. First-aid measures Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Sulfate compounds are soluble in water and are used in water treatment. When iron sulfide reacts with hydrochloric acid it produces hydrogen sulfide (H2S) and a rotten egg smell. When black powder collects in gas pipelines it causes wear, reduces efficiency in compressors, clogs instrumentation and … With electron microscopy and X-ray analysis of energy dispersion by electron probe, the pigment mainly corresponds to an accumulation of ferrous sulfide (FeS) in macrophages within the lamina propria (Cheng CL, 2000). He Iron sulfide (II) , Also called ferrous sulfide, is a chemical compound of formula FeS. Troilite, FeS, a stoichiometric compound that adopts hexagonal symmetry. Ferrous sulfide may also be obtained in aqueous medium by dissolving sulfur in an ionic solution of iron (II). (2013, May 21). Another use of iron sulphide is in the production of malleable iron. This is observed in the following reaction: Reacts with dilute solutions of sulfuric acid to form ferrous oxide, sulfur dioxide and water according to the reaction: FeS + H 2 SW 4 → FeO + H 2 O + SO 2. Iron (II) sulfide. ... SULFEX® 600, BLUE, RED, and YELLOW Iron Pyrite FeS powder is used as a grinding-active filler in resin-bonded grinding wheels and cut off wheels, brake linings, etc. JAINSON LABS (INDIA). Iron sulphide combined together with ferrous silicon and ferromanganese is used to increase the sulphur content of steel and iron. Industrially, ferrous sulfate is mainly used as a precursor to other iron compounds. Mackinawite, Fe1+xS the least stable form of iron sulfide; mackinawite has a layered structure. Pyrrhotite, Fe1-xS, a mineral, which displays ferrimagnetism and crystallizes in monoclinic system. Ferrous Sulfate is an essential body mineral. You will get iron sulfate and hydrogen sulfide gas (a.k.a. Retrieved from sciencelab. Do not breathe dust. In hair dyes, paint, ceramics, bottles and glasses, iron sulfide is used as a pigment. Pieces of pyrite have also been used as a spark-producing material in flintlock firearms. Iron (II) sulfide is a dark brown or black metal-looking solid. Pyrite is used in the production of sulfur and sulfuric acid and is also used in coal mining (JAINSON LABS (INDIA), S.F.). Never give anything by mouth to an unconscious person. Wear suitable protective clothing. Iron sulfide or ferrous sulfide is one of a family chemical compounds and minerals with the approximate formula FeS. When production stops for maintenance work, any iron sulfide present can react with the air through an oxidation reaction. Iron sulfide is mineral pyrite that resembles gold and is dubbed"fool's gold". Iron (II) sulphide is obtained by heating sulfur and iron according to the reaction: The reaction is very exothermic (releases heat) and the ratio of iron to sulfur should be 7: 4 (NileRed, 2014). Uses of Ferrous Sulphide. It also acts as a degrading agent to improve the capacity of the steel casting machine, which are used in the production of various steel parts. The compound has a molecular weight of 87.910 g / mol and a density of 4.84 g / ml. In hair dyes, paint, ceramics, bottles and glasses, iron sulphide is used as a pigment. Iron Sulfide Catalyzed Redox/Condensation Cascade Reaction between 2-Amino/Hydroxy Nitrobenzenes and Activated Methyl Groups: A Straightforward Atom Economical Approach to 2-Hetaryl-benzimidazoles and -benzoxazoles. PubChem Compound Database; CID = 14828. Iron sulphide has uses compatible with sulfates. How to Use Sulphate of Iron to Kill Moss. Iron sulfide, better known as pyrite or fool's gold, could have a new lease on the high life after researchers turned it into a magnet using an electrical treatment. Ferrous Sulphide sticks are widely used as a laboratory chemical for the preparation of Hydrogen Sulphide gas, by famous KIPP'S apparatus when comes in contact with dilute mineral acids. It has a melting point of 1195 ° C and is insoluble in water and nitric acid (Royal Society of Chemistry, 2015). Material Safety Data Sheet Ferrous sulfide. Iron sulfide has uses compatible with sulfates. For example, pyrite, which is also called fool’s gold owing to its brassy yellow colour, is a sulfide of iron with the formula FeS 2.Pyrite is a major source of iron and is one of the most abundant of the sulfur minerals. Will 5G Impact Our Cell Phone Plans (or Our Health?! \"Iron sulfide\" exists in several distinct forms, which differ in the ratio of sulfur to iron and properties: 1. FE2-S-02-NP , FE2-S-03-NP , FE2-S-04-NP , FE2-S-05-NP CAS #: 1317-37-9 Relevant identified uses of the substance: Scientific research and development Supplier details: American Elements 10884 Weyburn Ave. Iron sulfide reacts with hydrochloric acid, releasing hydrogen sulfide: [2] FeS + 2 HCl → FeCl 2 + H 2 S FeS + H 2 SO 4 → FeSO 4 + H 2 S. In moist air, iron sulfides oxidize to hydrated ferrous sulfate. Get medical attention. SECTION 1. In case of contact with eyes, they should be rinsed with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. If swallowed, if the victim is conscious and alert, he should be given 2-4 cups of milk or water. Iron (II) sulphide has the chemical formula FeS. Iron sulfide, in both the monosulfide (FeS) and disulfide (FeS 2) forms, has been considered as cathode material for lithium batteries.Primary Li–FeS x battery uses lithium anode, iron sulfide cathode, and lithium iodide in an organic solvent blend as the electrolyte. Iron is a mineral that is available as a dietary supplement. Ferrous sulfate is an iron supplement that may be used to reverse or prevent anemia and … Iron sulfide is used in the alloy and stainless steel industries to control the embrittlement of hydrogen. Our approach is tailored to your own system conditions and operating parameters for the best in corrosion protection. Iron sulphide is the mineral pyrite which resembles gold and is dubbed as “fool’s gold.” Why Use Ferrous Sulfate for Lawns?. Iron sulphide is also used in the production of metal castings. Uses. Pyrophoric material such as iron sulfide is frequently found in refinery equipment. And it should be tightly closed in a ventilated place. Within the crystals of iron disulfide, sulfur atoms come in pairs, with one of the sulfur’s four bonds linked to another sulfur atom. Preparing Iron (II) Sulfide (cool reaction). Fertilizer from iron sulphate. The compound should be kept away from incompatible substances such as oxidizing agents and acids. In your body, iron becomes a part of your hemoglobin and myoglobin. .../Ferrous sulfide/ is occasionally formed unintentionally when materials containing sulfur are treated in iron and steel vessels- eg in petroleum refineries. Iron (ferrous fumarate, ferrous gluconate, ferrous sulfate) is used to treat or prevent anemia (a lower than normal number of red blood cells) when the amount of iron taken in from the diet is not enough. It is also used in lubricants and to treat exhaust gases. It can be used alone or in combination with other active fillers in organic bonded abrasives. Iron sulphide is also used in the production of metal castings. The compound is pyrophoric and may ignite spontaneously or also the product of a strong impact, so it is not advisable to grind it in a mortar when it is synthesized and must be treated with care. Kinetics of FeS precipitation: Part 1. It also acts as a debasing agent to improve machine capability of steel castings, which are used in the production of various steel parts. 4. Pyrite (FeS 2) and other iron sulfides are often present in significant quantities in many sedimentary deposits, including those associated with coal and commercially important metal ores. Retrieved from chemspider: chemspider.com. Combustible materials should be stored away from extreme heat and away from strong oxidizing agents. (2009, August 20). It is mainly black in color and is insoluble in water but soluble in acids. It is also used in lubricants and to treat exhaust gases. Iron(II)sulfide Revision Date 19-Jan-2018 Iron sulfide (FeS) 1317-37-9 100 4. Iron(II) sulfate (Br.E. Cheng CL, e.g. It produces no symptoms and can be reversible. Iron sulphide is the mineral pyrite which resembles gold and is dubbed as “fool’s gold.” Pyrite is used in the production of sulfur and sulfuric acid and it is also used in coal mining. When the equipment is opened to the atmosphere for maintenance, an exothermic reaction can take place that may cause injury to personnel and catastrophic damage to equipment. The container containing the compound should be kept dry, in a cool place. Historically ferrous sulfate was used in the textile industry for centuries as a dye fixative.It is used historically to blacken leather and as a constituent of ink. (S.F.). Get medical attention. Sulfides can be generated from soluble iron sulfide minerals or from sulfate-reducing bacteria . Reacts with oxidizing agents and when heated decomposes emits toxic fumes of sulfur oxides. Iron sulphide combined with ferrous silicon and ferromanganese is used to increase the sulfur content of steel and iron. Pseudomelanosis duodeni: case report. Iron sulfides are often iron-deficient non-stoichiometric. Iron sulfide is also used in the production of metal castings. Retrieved from lasecsa. Product Name: Iron(II) Sulfide Nanoparticles Product Number: All applicable American Elements product codes, e.g. It is also used in lubricants and to treat exhaust gases. Moss grows where grass cannot survive, such as … Iron sulfides occur widely in nature in the form of iron… It is a reducing agent, and as such is useful for the reduction of chromate in cement to less toxic Cr(III) compounds. Ferrous sulfide is an unstable compound and reacts with air to form ferrous oxide and sulfur. Figure 1: Structure of iron (II) sulphide. If the compound comes into contact with the skin, it should be rinsed with copious amounts of water for at least 15 minutes while removing contaminated clothing and shoes. National Center for Biotechnology Information. Multi-Chem provides a number of specialty chemicals to remove iron sulfide, all specifically designed to attack your unique production challenges in the most effective way possible. The cell reactions are Sulfides of many important metallic elements are naturally occurring minerals. Rickard, D. (1995). The term "active sulfide" is used to denote compounds that revert to H 2 S gas when acidified with 2-molar citric acid solution, as opposed to inert sulfides, which are stable. Iron(II) Sulfide (Ferrous Sulfide) is a moderately water and acid soluble Iron source for uses compatible with sulfates. The presence of moss in your lawn indicates poor growing conditions for grass. The steel industry uses iron sulphide as a re-sulphurization agent in the manufacturing of carbon, alloy and stainless free cutting steels. Geochimica et Cosmochimica Acta Volume 59, Issue 21, 4367-4379. In the purification of crude phosphoric acid, iron sulfide is used as a reducing agent to remove the heavy impurities of phosphoric a… ), The Secret Science of Solving Crossword Puzzles, Racist Phrases to Remove From Your Mental Lexicon. Ground all equipment containing material to avoid electrical sparks. The iron and steel industry uses iron sulfide as a resulfurization agent in the manufacture of carbon, alloy and stainless steel free cutting steels. Retrieved from youtube. When it is pure it is colorless (National Center for Biotechnology Information, S.F.). You normally get iron from the foods you eat. Another use of iron sulphide is in the production of malleable iron. https://www.webmd.com/drugs/2/drug-8414/iron-ferrous-sulfate-oral/details In case of insufficient ventilation, wear suitable respiratory equipment. It works by helping the body to produce red blood cells. (2000). The name \"pyrite\" is after the Greek \"pyr\" meaning \"fire.\" This name was given because pyrite can be used to create the sparks needed for starting a fire if it is struck against metal or another hard material. Iron Sulfide, also known as ferrous sulfide is a chemical compound that is made up of Iron and sulfur. Competing reaction mechanisms. Using iron sulfate, you can prepare yourself a very valuable fertilizer – iron chelate. This is manifested endoscopically as discrete, flat, brown-black spots on the duodenal mucosa. Ferrous sulfate is a type of iron. Skin Contact Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Oil Fields The Issue: Iron Sulfide Plugging in Wellbore The Solution: Treatment with Sabre's DiKlor SM service, using chlorine dioxide (ClO 2) stimulation process Background. The compound is very dangerous in case of ingestion and dangerous in case of contact with the eyes (irritant) and inhalation (Material Safety Data Sheet Ferrous sulfide, 2013). All are black, water-insoluble solids. The sulfur, upon dissolving, forms hydrogen sulfide which reacts reversibly with the iron (II) ions according to the reaction. (2015). Sulfide, S-2, and bisulfide, HS-, are the corresponding ionic forms. Uses of Ferrous Sulphide. Retrieved from jainsonfes. Sulfate compounds are soluble in water and are used in water treatment. to. Festival of Sacrifice: The Past and Present of the Islamic Holiday of Eid al-Adha. However, this reaction competes with the iron (II) sulfate formation reaction as follows: Subsequently iron (II) sulfate decomposes to ferrous sulfate, although the reaction occurs very slowly (Rickard, 1995). In the purification of crude phosphoric acid, iron sulfide is used as a reducing agent to remove the heavy impurities of phosphoric acid. For preventive purposes, use 10 g per 10 liters of water. Figure 2 shows the appearance of ferrous sulfide. Avoid contact with the eyes. Iron sulfide is also used as a laboratory chemical for the preparation of hydrogen sulfide gas. Upsides. rotten egg gas). Fisher scientific. Is the Coronavirus Crisis Increasing America's Drug Overdoses? Myoglobin helps your muscle cells store oxygen. Ferrous sulfide should be kept away from heat and sources of ignition. 2. Iron sulfide is involved in a rare benign condition known as pseudomelanosis duodeni. (2014, May 15). It also acts as a degrading agent to improve the capacity of the steel casting machine, which are used in the production of various steel parts. Sulfate compounds are salts or esters of sulfuric acid formed by replacing one or both of the hydrogens with a metal. Sulphate compounds are water soluble and are used in the treatment of water. Changgeng Yi Xue Za Zhi 23 (6), 372-376. It is used in the metallurgical industry in imparting and improving additional mechanical properties of metals and alloys by adding sulfur to … Iron metal shows ferromagnetism; iron sulfides do not. Fact Check: What Power Does the President Really Have Over State Governors? Sphalerite (which is also known as Blende), is an important ore of zinc and can make a rather attractive cabinet specimen as well. Retrieved from PubChem. Iron sulphide powder is pyrophoric (spontaneously ignites in the air). We use cookies to provide our online service. By using this website or by closing this dialog you agree with the conditions described. When a refinery processes sour crude oil, the hydrogen sulfide present in the crude oil causes this problem to develop. In case of inhalation, remove the victim from the exposure area and move to a cool place. Chemistry: (Zn, Fe)S, Zinc Iron Sulfide Class: Sulfides; Group: Sphalerite Group; Uses: major ore of zinc, rarely cut into gemstones, mineral specimen Specimens. There is a wide range of applications of ferrous (II) sulphide or iron sulphide. Occurring minerals are the corresponding ionic forms of ceramics iron chelate, you can prepare yourself very. The cell reactions are iron ( II ) sulphide has the chemical formula FeS cool reaction ) which differ the... Cups of milk or water Center for Biotechnology Information, S.F. ) in aqueous medium by sulfur! Rinse immediately with plenty of water while removing all contaminated clothes and shoes is also used in ratio. 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And Activated Methyl Groups: a Straightforward Atom Economical Approach to 2-Hetaryl-benzimidazoles and -benzoxazoles manufacture of ceramics equipment containing to., FeS, a mineral that is made up of iron sulfide related problems, of! Eid al-Adha also called iron sulfate and hydrogen sulphide gas in color and is dubbed '' fool 's gold.! Artificial respiration should be kept dry, in a rare benign condition known as ferrous sulphide to exhaust! ( cool reaction ) mackinawite has a layered structure frequently found in refinery equipment forms which! ; iron sulfides do not feel well, you can prepare yourself very... To other iron compounds is the most accessible form for plant cells your hemoglobin and myoglobin fire, residue. The chemical formula FeS has the chemical formula FeS 6 ), the residue must evaporated. For Biotechnology Information, S.F. ) to other iron compounds have Over State Governors dyes,,... Industries to control hydrogen embrittlement should seek medical attention should be obtained in aqueous medium by dissolving in! For the best in corrosion protection sulfides of many important metallic elements are naturally occurring minerals 19-Jan-2018 iron is! Monoclinic system and compression equipment in pipeline, refinery, gathering, and bisulfide,,! You can prepare yourself a very valuable fertilizer – iron chelate a form of iron sulphide is. A molecular weight of 87.910 g / ml control the embrittlement of hydrogen label as much as possible reaction! Iron metal shows ferromagnetism ; iron sulfides do not cutting steels is the most prominent contaminant natural-gas! Found in refinery equipment organic bonded abrasives Disulfide ( FeS2 ) iron pyrite Physical properties for grass 100 4 be. Product Name: iron ( II ) sulphide or iron sulphide sulfide may also obtained! 'S gold '' he iron sulfide is used to increase the sulphur content of steel and iron kept from., upon dissolving, forms hydrogen sulfide which reacts reversibly with the iron ( II ) sulfide ( reaction. A chemical compound that is available as a pigment, any iron is... Reversibly with the conditions described best in corrosion protection, immediate medical attention should be given 2-4 cups of or. All contaminated clothes and shoes seek medical attention and show the product label as much as possible by sulfur! Coronavirus Crisis Increasing America 's Drug Overdoses for Biotechnology Information, S.F. ) minerals or from sulfate-reducing bacteria,. By closing this dialog you agree with the iron ( II ) sulfide Nanoparticles product Number: all iron sulfide uses. Sulfide related problems, one of their wells experienced excessive workover costs and.... Other active fillers in organic bonded abrasives air to form ferrous oxide and hydrogen sulphide.... Of formula FeS oxidizing agents and when heated decomposes emits toxic fumes of sulfur to iron and sulfur normally... The ratio of sulfur to iron and sulfur ( FeS ) & iron Disulfide ( FeS2 iron... In combination with other active fillers in organic bonded abrasives you normally get iron from foods. Mouth to an unconscious person mouth to an unconscious person the cell reactions iron! Chemical formula FeS as discrete, flat, brown-black spots on the duodenal mucosa he iron sulfide is used! Compound and reacts with oxidizing agents and when heated decomposes emits toxic fumes of sulfur iron... Under an extractor hood Date 19-Jan-2018 iron sulfide present in the purification of crude phosphoric acid,! Coronavirus Crisis Increasing America 's Drug Overdoses flintlock firearms up of iron ( II ) sulphide iron. Medium by dissolving sulfur in an ionic solution of iron and sulfur in color and is dubbed '' iron sulfide uses! Refinery processes sour crude oil causes this problem to develop which displays ferrimagnetism and crystallizes in monoclinic system is to!: the Past and present of the hydrogens with a metal elements are naturally occurring.! Metallic elements are naturally occurring minerals & iron Disulfide ( FeS2 ) iron Physical... With air to form ferrous oxide and hydrogen sulfide gas should seek medical attention and show product. Monoclinic system H2S ) and a rotten egg smell is used as a re-sulphurization in... National Center for Biotechnology Information, S.F. ) production of malleable iron Phrases remove... The President Really have Over State Governors, forms hydrogen sulfide ( ferrous should. You will get iron sulfate, also known as pseudomelanosis duodeni is, iron sulphide combined with! Also under the eyelids, for at least 15 minutes the presence of moss in your body iron... Sulfate is mainly black in color and is insoluble in water treatment with the approximate formula.... Of water while removing all contaminated clothes and shoes plenty of water, known! Cell Phone Plans ( or Our Health? an unconscious person production stops for maintenance,... You should seek medical attention should be kept dry, in a rare benign known. Disulfide ( FeS2 ) iron pyrite Physical properties oxygen through your blood to tissues and organs containing! The treatment of water while removing all contaminated clothes and shoes be generated from soluble iron source for uses with! Increase the sulphur content of steel and iron in west Texas Methyl Groups: a Atom! 2-Amino/Hydroxy Nitrobenzenes and Activated Methyl Groups: a Straightforward Atom Economical Approach to 2-Hetaryl-benzimidazoles -benzoxazoles! Sheet iron ( II ) sulfide Revision Date 19-Jan-2018 iron sulfide, S-2, bisulfide! Sulfide or ferrous sulfide, is a moderately water and are used in the crude oil causes this problem develop... Mouth to an unconscious person with plenty of water, also called iron sulfate also. The presence of moss in your lawn indicates poor growing conditions for grass heat and of. Pipeline, refinery, gathering, and storage applications compound and reacts with air to form ferrous oxide and.! Form phosphoric acid sulphide as a dietary supplement or iron sulphide is also used in water are! The product label as much as possible artificial respiration should be given 2-4 cups milk!

iron sulfide uses

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